Michael Fuller
Cave 1, Panel 4, Glyph 192 (black kneeling figure). Photograph by Mike Chervinko
75: Iron = 0.2% +/- 0.012 and Aluminum = 99.797% +/- 0.005
76: Antimony = 87.28 ppm +/- 15.71, Tin = 45.48 ppm +/- 14, Cadmium = 18 ppm +/- 11.23, Silver = 114.37 ppm +/- 16.88, Zirconium = 71.77 ppm +/- 10.11, Iron = 1034.11 ppm +/- 73.03, Barium = 566.23 ppm +/- 56.48, and Strontium = 33.61 ppm +/- 4.14
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Cave 1, Panel 1, Glyph 82 (black upside down flyer). Photograph by Mike Chervinko.
57: Antimony = 47.7 ppm +/- 12.56, Tin = 17.41 ppm +/- 11.17, Zirconium = 42.59 ppm +/- 7.89, Iron = 732.51 ppm +/- 52.37, Barium = 443.4 ppm +/- 45.84, and Strontium = 11.42 ppm +/- 2.79
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Cave 1, Panel 2, Glyph 25 (Black abstract)
pXRF 14: Iron = 0.168% +/- 0.011 and Aluminum = 99.83% +/- 0.004
pXRF 21: Iron = 0.171% +/- 0.011 and Aluminum = 99.827% +/- 0.004
pXRF 47: Antimony = 48.51 ppm +/- 12.38, Tin = 22.37 ppm +/- 11.03, Zirconium = 37.06 ppm +/- 7.69, Iron = 1052.99 ppm +/- 59.76, Manganese = 59.89 ppm +/- 36.34, Barium = 431.08 ppm +/- 45.02, and Strontium = 11.17 ppm +/- 2.74
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Cave 1, Panel 1, Red Horn pictograph. This was remeasured (in the center of the figure) to compare with data from our first study.
pXRF 63: Antimony 86.46 ppm +/- 16.73, Tin = 51.14 ppm +/- 15.02, Cadmium = 28.49 ppm +/- 12.16, Silver = 137.57 ppm +/- 18.22, Zirconium = 55.66 ppm +/- 10.47, Iron = 449.88 ppm +/- 56.74, Barium = 555.71 ppm +/- 60.02, Strontium = 22.06 ppm +/- 4.02. Palladium and Tungsten were recorded in 2020 study , but not in this sample indicating that their distribution in the pigment is not uniform. We used the same Niton pXRF equipment that had been standardized before we entered the cave.
Infrared photograph by Mike Chervinko.
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Cave 1, Panel 2, Glyph 18 Black raised arms
pXRF 12: Iron = 0.27% +/- 0.015, Aluminum = 99.726 +/- 0.006
pXRF 22: Iron = 0.274% +/- 0.013, Aluminum = 99.723% +/- 0.005
pXRF 42: Antimony = 83.72 ppm +/- 13.58, Tin = 53.93 ppm +/- 12.18, Cadmium = 17.56 ppm +/- 9.71, Zirconium = 21.81 ppm +/- 8, Nickel = 57.06 ppm +/- 24.88, Iron = 1624.26 ppm +/- 76.83, Manganese = 65.01 ppm +/- 39.87, Barium = 555.67 ppm +/- 48.84, Strontium = 14.7 ppm +/- 3.04
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Cave 1, Panel 1, with glyph 59 on the left edge of the panel. Digital photograph by Mike Chervinko.
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Gated entrance. [Not Caesarea] Photograph by Richard Orr.
Cave 1, Panel 2, Glyph 26, Single black figure in bow of a canoe
pXRF 16: Iron = 0.275% +/- 0.016, Aluminum = 99.719% +/- 0.007
pXRF 18: Iron - 0.225% +/- 0.02, Aluminum - 99.772 +/- 0.02
Cave 1, Panel 2, Glyph 31 (Black Archer bow down). Photograph by Mike Chervinko
pXRF 17: Iron = 0.125% +/- 0.009, and Aluminum = 99.852% +/- 0.003
pXRF 19: Iron = 0.127% +/- 0.009 and Aluminum = 98.871% +/- 0.003
pXRF 48: Antimony = 48.19 ppm +/- 12.04, Tin = 26.8 ppm +/- 10.79, Zirconium = 25.18 ppm +/- 7.73, Iron = 955.15 ppm +/- 55.83, Manganese = 59.55 ppm +/- 34.61, Barium = 359.62 ppm +/- 43.34, and Strontium = 9.49 ppm +/- 2.61
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Body sherd along the neck and shoulder of a Darnell Cord Marked jar that was left behind by indiscriminate diggers on the floor of Cave 1. Thickness = 8.6 mm; coarse grit temper.
Chapman (1980:280-281) noted that the type site for this pottery type is Graham Cave in Montgomery County, MO (located immediately to the west). The shape and manufacture of the Darnell Cord Marked is clearly in the Late Woodland (AD 400 to 900) or Terminal Late Woodland (AD 900 to 1000) time range.
Cave 1, Panel 2, Glyph 15, Black Serpent. Photograph by Mike Chervinko.
pXRF 8: Iron = 0.114% +/- 0.011 and Aluminum 99.884% +/- 0.003
pXRF 27: Iron = 0.137% +/- 0.009, and Aluminum 99.862% +/- 0.003
pXRF 39: Antimony = 54.53 ppm, Tin = 30.1 ppm +/- 10.78, Cadmium = 14.82 ppm +/- 8.77, Zirconium = 16.16 ppm +/- 7.18, Iron = 763.06 ppm +/- 50.79, Manganese = 64.16 ppm +/- 35.15, Barium = 437.58 ppm +/- 43.63, Strontium = 13.08 ppm +/- 2.71
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Panel 1 in Cave 1 showing the body of a slain, antlered river otter Spirit Being. Its body is stacked on top of a slain, antlered wolf. The antlers are a convenient way to indicate "masculine" gender. Photograph by Mike Chervinko.
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Cave 1, Panel 2, black archer facing right. pXRF 6: Niobium = 0.016% +/- 0.002, Iron = 0.152% +/- 0.009, Aluminum = 99.83% +/- 0.003 and pXRF 32: Iron = 1.061% +/- 0.027, Aluminum = 98.84% +/- 0.02
pXRF 33: Antimony = 43.02 ppm +/- 12.29, Tin = 29.68 ppm +/- 11.09, Zirconium = 35.19 ppm +/- 7.67, Zinc = 11.74 ppm +/- 6.53, Iron = 6763.04 ppm +/- 140.29, Manganese = 69.82 ppm +/- 37.75, Barium = 399.06 ppm +/- 44.7, Strontium = 18.12 ppm +/- 2.93, and Rubidium = 3.46 ppm +/- 1.82
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Cave 2, Panel 4, Glyph 526 (Red archer)
79: Antimony = 50.7 ppm +/- 13.71, Tin = 36.36 ppm +/- 12.4, Zirconium = 37.59 ppm +/- 8.5, Iron = 3438.59 ppm +/- 112.13, Barium = 417.96 ppm +/- 49.65, and Strontium = 5.97 ppm +/- 2.84
87: Iron = 0.684% +/- 0.021 and Aluminum = 99.313% +/- 0.013
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Cave 1, Panel 1, Glyph 95 (black singer with rattle).
60: Antimony = 27.29 ppm +/- 11.42, Tin = 20.79 ppm +/- 10.34, Zirconium = 17.69 ppm +/- 6.98, Nickel = 43.46 ppm +/- 21.01, Iron = 604.3 ppm +/- 45.02, Barium = 352.01 +/- 41.85, and Strontium = 8.15 ppm +/- 2.48Cave 1, Panel 1, Glyph 93 (black singer left side).61: Antimony = 41.71+/- 12.3, Tin = 30.45 ppm +/- 11.11, Zironium = 27.65 ppm +/- 7.56, Iron = 692.52 ppm +/- 50.37, Barium = 383.63 ppm +/- 44.65, and Strontium = 10.93 ppm +/- 2.73
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Cave 1, Panel 1, Glyph 58 (black woman)
p XRF 30: Iron = 3.29% +/- 0.067 and Aluminum = 96.707% +/- 0.058
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Cave 1, Panel 1, Glyph xxx (black turkey by woman's ear)
pXRF 31: Iron = 2.923% +/- 0.053 and Aluminum = 97.075 +/- 0.046
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Cave 1, panel 1, Glyph xx (turkey right of frog). pXRF 53: Antimony = 100.88 ppm +/- 16.99, Tin = 53.85 ppm +/- 15.12, Cadmium = 27.35 ppm +/- 12.2, Silver = 132.22 ppm +/- 18.25, Zirconium = 61.59 ppm +/- 10.61, Iron = 573.83 pp +/- 62.45, Manganese = 81.05 ppm +/- 50.09, Barium = 549.42 ppm +/- 60.24, Strontium = 20.89 ppm +/- 3.99, and Rubidium = 4.7 ppm +/- 2.48
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Cave 1, Panel 2, Glyph 16. Red pigment pictograph of a long tailed quadruped with round paws - easily identified as a Panther. Photograph by Michael Fuller.
pXRF 9: Iron = 1.439% +/- 0.035, Aluminum = 98.559% +/- 0.026
pXRF 26: Iron = 1.347% +/- 0.032, Aluminum = 98.652% +/- 0.024
pXRF 40: Antimony = 48.22 ppm +/- 11.84, Tin = 26.46 ppm +/- 10.58, Zirconium = 23.63 ppm +/- 7.2, Iron = 6679.23 ppm +/- 133.85, Barium = 343.94 ppm +/- 42.53, Strontium = 13.9 ppm +/- 2.7
Cave 1, Panel 1, Glyph 64 (black frog)
pXRF 51: Antimony = 41.03 ppm +/- 12.07, Tin = 26.39 ppm +/- 10.85, Zirconium = 25.69 ppm +/- 7.39, Iron = 616.32 ppm +/- 47.2, Barium = 349.29 ppm +/- 43.64, and Strontium = 7.99 ppm +/- 2.59
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Cave 1, panel 1, Glyph xx (black snake below frog)
52: Antimony = 55.4 ppm +/- 14.06, Tin = 42.9 ppm +/- 12.74, Cadmium = 20.21 ppm +/- 10.32, Zirconium = 33.17 ppm +/- 8.63, Iron = 728.48 ppm +/- 57.99, Barium = 378.26 ppm +/- 50.39, and Strontium = 11.27 ppm +/- 3.09
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Taking pXRF readings in Cave 1. Photograph by Mike Chervinko.
Cave 1, Panel 1, Glyph 134 (black bead spitter). Photograph by Mike Chervinko
66: Antimony = 55.17 ppm +/- 14.33, Tin = 34.4 ppm +/- 12.9, Zirconium = 46.53 ppm +/- 9.05, Iron = 502.73 ppm +/- 51.7, Barium = 380.59 ppm +/- 51.46, and Strontium = 20.25 ppm +/- 3.47
70: Iron = 0.077% +/- 0.009, and Aluminum = 99.92% +/- 0.002
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Cave 2, Panel 6, Glyph xxx (Red Drying rack). Photograph by Mike Chervinko
83: Antimony = 58.82 ppm +/- 13.25, Tin = 44.75 ppm +/- 11.98, Cadmium = 18.15 ppm +/- 9.67, Zirconium = 37.26 ppm +/- 8.16, Iron = 4987.55 +/- 128.62, Barium = 423.5 ppm +/- 47.69, and Strontium = 7.91 ppm +/- 2.70
86: Iron = 0.36% +/- 0.024 and Aluminum = 99.638% +/- 0.006
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Cave 2, Panel 4, Glyph 527 (red lightning panther)
80: Antimony = 62.51 ppm +/- 13.34, Tin = 33.04 ppm +/- 11.89, Zirconium = 41.69 ppm +/- 8.27, Iron = 1554.31 ppm +/- 75.24, Barium = 408.48 ppm +/- 47.87, and Strontium = 9.34 ppm +/- 2.86
88: Iron = 0.259% +/- 0.015 and Aluminum = 99.737% +/- 0.005
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Deeper chamber of (below room with pictographs)with 1949 inscription. Photograph by Richard Orr.
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Cave 1, panel 1, Glyph 73 (black stag deer)
pXRF 54: Antimony = 48.59 ppm +/- 12.43, Tin = 23.3 ppm +/- 11.13, Zirconium = 19.18 ppm +/- 7.5, Iron = 1099.56 ppm +/- 61.12, Barium = 394.75 ppm +/- 45, and Strontium = 12.61 +/- 2.79
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Cave 1, panel 1, Glyph xxx (black animal above stag deer)
55: Antimony = 79.74 ppm +/- 15.78, Tin = 40.66 ppm +/- 14.15, Silver = 136.44 ppm +/- 17.3, Zirconium = 45.38 ppm +/- 9.75, Iron = 827.9 ppm +/- 67.48, Barium = 567.2 ppm +/- 57.15,
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Cave 1, panel 1, Glyph 74 (black running archer)
56: Antimony = 94.54 ppm +/- 15.97, Tin = 58.08 ppm +/- 14.31, Cadmium = 23.01 ppm +/- 11.44, Silver = 124.51 ppm +/- 17.15, Zirconium = 53.57 ppm +/- 9.87, Iron = 384.22 ppm +/- 51.03, Barium = 511.01 ppm +/- 56.6, and Strontium = 15.84 ppm +/- 3.59
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Cave 1, Panel 2, Left facing red archer:
pXRF 4: Iron = 3.843% +/- 0.069, and Aluminum = 96.147% +/- 0.062
pXRF 31: Iron = 2.923% +/- 0.053 and Aluminum = 97.075% +/- 0.046
pXRF 34: Antimony = 58.22 ppm +/- 12.58, Tin = 21.07 ppm +/- 11.15, Zirconium = 17.78 ppm +/- 7.49, Iron = 21300.1 ppm +/- 248.84, Barium = 441.76 ppm +/- 45.47, and Strontium = 11.7 ppm +/- 2.77
Cave 1, Panel 2, red squatting deer under red archer
pXRF 5: Iron = 2.867% +/- 0.055 and Aluminum 97.131% +/- 0.055
pXRF 30: Iron = 3.29% +/- 0.067 and Aluminum = 96.707% +/- 0.058
pXRF 35: Antimony = 77.93 ppm +/- 14.26, Tin = 50.88 ppm +/- 12.84, Cadmium = 16.77 ppm +/- 10.24, Silver = 102.94 ppm +/- 15.33, Zirconium = 28.44 ppm +/- 8.54, Iron = 25342.68 ppm +/- 301.98, Barium = 537.56 ppm +/- 51.46, Strontium = 9.82 ppm +/- 3.04
Cave 1, Panel 2 with red pigment shield overlapping several black pigment figures. Black arrows piece the shield on the right site. pXRF 7: Iron = 0.567% +/- 0.022 and Aluminum = 99.429% +/- 0.012
Photograph by Michael Fuller.
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Deeper chamber (below room with pictographs) has many historic signatures and need to be carefully checked for any evidence of rock art. Photograph by Richard Orr.
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Cave 1, Panel 1, Glyph xxx (black panther to left of deer head dress dancer). Photograph by Mike Chervinko.
59: Antimony = 52.77 ppm +/- 12.46, Tin = 23.8 ppm +/- 11.09, Zirconium = 26.7 ppm +/- 7.59, Iron = 721.42 ppm +/- 51.39, Barium = 372.5 ppm +/- 44.81, and Strontium = 11.27 +/- 2.75
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Cave 1, Panel 2, Glyph xx (Black Panther?)
pXRF 15: Iron = 0.163% +/- 0.01 and Aluminum = 99.834% +/- 0.004
pXRF 20: Iron = 0.171% +/- 0.011 and Aluminum = 99.826% +/- 0.004
pXRF 46: Antimony = 48.47 ppm +/- 12.82, Tin = 22.95 ppm +/- 11.46, Zirconium = 24.79 ppm +/- 7.81, Iron = 956 ppm +/- 59.47, Barium = 421.74 ppm +/- 46.56, and Strontium = 13.56 ppm +/- 2.91
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Cave 1, Panel 1, Big Horn. We remeasured the long nose god Maskette to compare with data from our first study. pXRF 64: Antimony = 109.74 ppm +/- 22.6, Tin = 65.29 ppm +/- 20.44, Cadmium = 29.73 ppm +/- 16.26, Silver = 217.12 +/- 25.38, Zirconium = 59.9 ppm +/- 14.03, Iron = 834.37 ppm +/- 95.25, Barium = 665.1 ppm +/- 80.93, Strontium = 14.55 ppm +/- 5. Palladium was recorded in 2020, but not in 2023 study indicating that the element was not uniformly distributed in the pigment.
Digital photograph by Mike Chervinko.
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Cave 1, Panel 1, Glyph 139 (Black dancer on dead mace man)
67: Antimony = 81.67 ppm +/- 17.93, Tin = 78.04 ppm +/- 16.5, Cadmium = 30.05 ppm +/- 13.12, Silver = 134.66 ppm +/- 19.56, Zirconium = 52.47 ppm +/- 11.17, Iron = 1274.67 ppm +/- 91.19, Barium = 544.58 ppm +/- 64.43, and Strontium = 13.51 ppm +/- 3.98
69: Iron = 0.227% +/- 0.022 and Aluminum = 99.768% +/- 0.005
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Cave 1, Panel 1, Glyph 105 (black pigment man). Photograph by Mike Chervinko
62: Antimony = 46.61 ppm +/- 12.09, Tin = 29.82 ppm +/- 10.86, Cadmium = 14.19 ppm +/- 8.85, Zirconium = 21.74 ppm +/- 7.31, Iron = 727.36 ppm +/- 50.118, Barium = 36`.77 ppm +/- 43.56, and Strontium = 8.73 ppm +/- 2.6
72: Iron = 0.126% +/- 0.01 and Aluminum 99.87% +/- 0.003
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Cave 2, Panel 4, Glyph 519 (faint Red vulva or tri-glyph)
81: Antimony = 48.25 ppm +/- 12.16, Tin = 28.36 ppm +/- 10.92, Zirconium = 29.71 ppm +/- 7.46, Iron = 3422.89 ppm +/- 99.72, Barium = 399.9 ppm +/- 44.05, and Strontium = 8.68 ppm +/- 2.61
90: Iron = 0.519% +/- 0.023 and Aluminum = 99.479% +/- 0.01
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Cave 1, Panel 1, Glyph 59. A complex series of overlapping black pictographs include the profile of an individuals (female?) overlain by one of several turkeys. Beneath the profile is a horizontal pictograph that has been interpreted in many ways. It could be the toothy mouth/vagina of a Spirit Being. Numerous lines above and belong the horizontal pictograph are interesting because several of the lower lines appear to be arrows with nocks and fletching. Could this be a bundle (burial or medicine?) that has been shot with arrows? It is also "open" on the left side as a clam shell that figures in one version of the Osage creation myth. Infrared photograph taking with a 720 nm filter. Infrared photograph by Mike Chervinko.
pXRF 50: Antimony = 56.85 ppm +/- 12.58, Tin = 25 ppm +/- 11.17, Zirconium = 30.46 ppm +/- 7.68, Iron = 497.56 ppm +/- 44.9, Barium = 381.72 ppm +/- 45.1, and Strontium = 11.15 ppm +/- 2.76
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Resharpened Etley point left behind by indiscriminate diggers on the floor of Cave 1. Length 86.49 mm, Width = 37.60 mm, Thickness = 10.93 mm, and weight = 31.60 grams.
Ray (2016:88 - 91) notes that many associated radiocarbon dates in Missouri and Illinois bracket this tool type from 2250 to 1950 BC. The pinkish chert is of local variety with fine bryozoan fossils. The pinkish tint (heat treatment?) is unusual for Etley points which are normally gray white.
Ray, Jack
2016 Projectile Point Types in Missouri and Portions of Adjacent States. Missouri Archaeological Society Special Publication 10.
Cave 2, Panel 5, Glyph 541 (Red tri-glyph)
82: Antimony = 58.21 ppm +/- 12.62, Tin = 37.6 ppm +/- 11.33, Zirconium = 28.95 ppm +/- 7.67, Iron = 1492.16 ppm +/- 70.12, Barium = 402.64 ppm +/- 45.34, and Strontium = 9.86 ppm +/- 2.72
91: Iron = 0.485% +/- 0.019 and Aluminum = 99.513% +/- 0.01
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Cave 1, panel 2, Glyph 20 red double headed (birthing?) animal
pXRF 13: Iron = 5.131% +/- 0.083, Aluminum = 94.864% +/- 0.076 and pXRF 23: Iron = 3.269% +/- 0.06, Aluminum = 96.729% +/- 0.053
pXRF 44: Antimony = 88.25 ppm +/- 13.41, Tin = 45.83 ppm +/- 11.93, Cadmium = 21.94 ppm +/- 9.61, Silver = 102.35 ppm +/- 14.3, Zirconium = 32.89 ppm +/- 8, Nickel = 55 ppm +/- 24.74, Iron = 39778.87 ppm +/- 352.15, Barium = 553.46 ppm +/- 48.08
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Cave 1, Panel 1, Glyph 93 (black figure holds deer headdress). Photograph by Mike Chervinko.
58: Antimony = 68.19 ppm +/- 14.77, Tin = 54.23 ppm +/- 13.4, Cadmium = 17.13 ppm +/- 10.7, Zirconium = 39.21 ppm +/- 9.09, Iron = 304.02 ppm +/- 44.59, Barium = 480.25 ppm +/- 53.23, and Strontium = 12.72 ppm +/- 3.28
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Cave 1, Panel 4, no number (black standing man in canoe). Mike Chervinko photograph.
73: Iron = 0.529% +/- 0.018 and Aluminum 99.463% +/- 0.018 [normal iron level]
78: Antimony = 70.97 ppm +/- 13.73, Tin = 39.63 ppm +/- 12.23, Zirconium = 46.1 +/- 8.52, Iron = 3913.14 +/- 117.67, Manganese = 85.77 +/- 41.61, Barium = 396.25 +/- 48.77, Strontium = 12.61 ppm +/- 3.03, and Rubidium = 3.39 ppm +/- 1.97
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Cave 2, Panel 6, Glyph 565 (Red HourGlass left)
84: Iron = 1.088% +/- 0.03, and Aluminum = 98.909% +/- 0.021
92: Antimony = 35 ppm +/- 11.96, Tin = 35.46 ppm +/- 10.91, Zirconium = 16.12 ppm +/- 7.22, Iron = 715.38 ppm +/- 49.73, Barium = 329.29 ppm +/- 43.31, and Strontium = 2.48
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Cave 1, Panel 2, Glyph 19 Red raised arms. pXRF 11: Lead = 0.003% +/- 0.001, Iron = 3.53% +/- 0.093, Aluminum = 96.465% +/- 0.082 and pXRF 24: Lead = 0.004% +/- 0.001, Iron = 5.206% +/- 0.088, Aluminum = 94.788% +/- 0.081
pXRF 43: Antimony = 63.71 ppm +/- 12.46, Tin = 30.69 ppm +/- 11.1, Zirconium = 15.48 ppm +/- 7.4, Zinc = 9.38 ppm +/- 6.14, Nickel = 46.69 ppm +/- 22.5, Iron = 25762.51 ppm +/- 269.77, Manganese = 64.78 ppm +/- 41.39, Barium = 435.56 ppm +/- 44.82, Strontium = 24.68 ppm +/- 3.12
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pXRF 45: Antimony = 71.41 ppm +/- 13.55, Tin = 36.6 ppm +/- 12.04, Cadmium = 17.09 ppm +/- 9.77, Zirconium = 33.03 ppm +/- 8.24, Iron = 1330.96 ppm +/- 70.94, Manganese = 59.63 ppm +/- 39.15, Barium = 443.35 ppm +/- 48.43, and Strontium = 19.64 ppm +/- 3.21
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Cave 1, Panel 2, Glyph 4 - dancing red fringe man
pXRF 32: Iron = 1.061% +/- 0.027, Aluminum = 98.84% +/- 0.02
pXRF 33: Antimony = 43.02 ppm +/- 12.29, Tin = 29.68 ppm +/- 11.09, Zirconium = 35.19 ppm +/- 7.67, Zinc = 11.74 pp, +/- 6.53, Iron = 6763.04 ppm +/- 140.29, Manganese = 69.82 ppm +/- 37.75, Barium = 44.7 ppm +/- 18.12, Strontium = 18.12 ppm +/- 2.93, and Rubidium = 3.46 ppm +/- 1.82
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Four examples of large mammal bones (deer, elk, beer) left behind by indiscriminate diggers on the floor of Cave 1. Three of the bones are split and resemble split bones examples from the Groeper shelter site.
Cave 1, Panel 1, Infrared photography by Mike Chervinko. Two warriors in elaborate regalia confront the rectangular shield warriors while cheered on by the mortally wounded giant warrior (Giver of Speech?).
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Cave 1, Panel 1, Glyph 120.Three arrows in the center of the back of the slain river otter.
pXRF 65: Antimony = 98.84 ppm +/- 19.38, Tin = 70.55 ppm +/- 17.62, Cadmium = 35.08 ppm +/- 14.11, Silver = 178.52 ppm +/- 21.43, Zirconium = 50.41 ppm +/- 11.89, Iron = 540.94 ppm +/- 69.97, Barium 623.02 ppm +/- 69.47, and Strontium = 12.63 ppm +/- 4.21
pXRF 71: Iron = 0.092% +/- 0.013, and Aluminum = 99.906% +/- 0.002
Cave 1, Panel 4, Glyph 400 (black small head guy)
74: Iron = 0.19% +/- 0.012 and Aluminum = 99.807% +/- 0.004 [normal level of iron]
77: Antimony = 85.15 ppm +/- 15.91, Tin = 64.18 ppm +/- 14.43, Cadmium = 22.29 ppm +/- 11.47, Silver = 123.58 ppm +/- 17.18, Zirconium = 48.99 ppm +/- 9.82, Iron = 1197.15 ppm +/- 78.64, Barium = 466.98 ppm +/- 56.43, and Strontium = 11.95 ppm +/- 3.46
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